• 专利附录
  • 专利说明
  • 权利要求
  • 类似技术
  • 同族专利
  • 引用文献
  • 法律状态
  • 优先权
    • 专利摘要:
    1507465 Silicon-coated glass PILKINGTON BROS Ltd 12 June 1975 [14 June 1974] 26522/74 Heading C1M [Also in Division C7] A coating comprising elemental silicon is formed on the surface 41 of a glass ribbon 21 by moving the glass 21 past a coating station while the glass temperature is at least 400‹C., supplying a silanecontaining gas to a zone 40, which zone extends transversely across the entire width of the ribbon, at substantially constant pressure throughout zone 40, and maintaining non-oxidizing conditions in the zone, which attains a temperature of at least 400‹C., so that silicon is deposited on the glass 21 by a pyrolysis reaction. The pyrolysis is preferably at 500-700‹C., the gas supplied preferably consisting of, by volume, 0À1-20% silane (preferably SiH 4 ), up to 10% H 2 , and 70-99À9% inert gas (e.g. N 2 ). The glass 21 may be coated in an annealing lehr (Fig. 10, not shown) or in a float glass tank (Fig. 3). In the latter embodiment gas is supplied to a supply duct 35, from where it passes to zone 40 through restrictor means 56, the restrictor means ensuring a pressure drop between duct 35 and zone 40 to allow a constant pressure to be attained across the entire width of ribbon 21. Zone 40 comprises carbon side and end walls 45 and 44, and roof 42 of compressed mineral fibre. Premature pyrolysis in duct 35 may be prevented by passing water through cooling ducts 31 and 36. The entire coating device may be raised or lowered to allow the lower edges 54, 61 to be close to the glass surface. The siliconcoated glass formed, having a coating thickness of, e.g., 250-1600Š, may be used in single or multiple glazing units.
    公开号:SU904513A3
    申请号:SU752147450
    申请日:1975-06-13
    公开日:1982-02-07
    发明作者:Джеймс Киркбрайд Бернард；Эндрю Дауни Роберт；Виктор Томассон Чарльз；Эрл Льюис Джозеф
    申请人:Пилкингтон Бразерз Лимитед (Инофирма)；
    IPC主号:
    专利说明:

    The invention relates to the coating of sheet glass, in particular to a method for coating sheet glass with silicon on one or both sides of the sheet to modify the properties of the glass with respect to transmission of radiation and reflection, as well as for decorative purposes. The invention also relates to a coating device designed to supply coating material in a gaseous state.
    A known method of producing a silicon coating on the surface of glass parts at a temperature of 400-700 C by pyrolysis of a mixture comprising silane, hydrogen and an inert gas with a gram-molecular ratio of the latter to hydrogen up to 1 [1].
    Also known is a device for applying a coating to glass, comprising a gas distributor installed across the glass ribbon, a gas pipeline, an elongated chamber communicating with the gas pipeline using gas flow restriction means [2].
    A disadvantage of the known method and device is the unevenness 5 of the resulting coating.
    The aim of the invention is to obtain a uniform coating.
    To achieve this goal, according to the method of obtaining a silicon coating on a glass surface with a temperature of 400-700 C by pyrolysis of a mixture comprising silane and inert gas, the coating is applied to a continuously moving tape of glass ·· 15 l across the entire width of a mixture of the following composition, vol. I:
    Silane '0.1-20
    Inert gas Else
    It is advisable to apply the coating from a mixture containing additional hydrogen - 2-10 vol.
    To achieve this goal, in a known device for performing a method including a support, a gas pipeline for supplying a coating material located across the glass dent and an open chamber, the gas pipeline is equipped with a water jacket and connected to the open chamber by a gas flow distributor.
    In this device, it is advisable to perform a gas flow distributor in the form of a series of vertical channels, install heat-insulating plates between the gas pipeline and the chamber, and perform the chamber with shaped walls.
    The proposed method can be used for coating of silicon, as well as a mixture of silicon with other materials.
    The preferred surface temperature of the glass for coating 6OO ~ 67O ° C.
    The silane contained in the coating mixture is pre-heated before coating to a temperature of 400 ° C, at which significant silane decomposition does not occur. The thickness of the applied coating can be from 250 to 600 A, the refractive index of the coating is 3.0-4.0.
    In FIG. 1 shows a device for making sheet glass on the surface of molten metal — showing the design of a bath for molten metal and a gas distributor that is installed across the path of movement of sheet glass near the output end of the device, vertical section, in FIG. 2 - gas distributor, section; in FIG. 3 - part of the gas distributor, an enlarged view; in FIG. 4 - the same, the side walls are shaped, and so that they form a cavity broadening in the direction of the open side of the chamber; in FIG. 5 same, the side walls forming the open side of the chamber have a different shape, in FIG. 6 - the same, the camera has an open side; in FIG. 7 design variant of a gas distributor for coating glass in an annealing glass furnace, cross section.
    The molten glass 1 is fed in the usual way along the channel 2 leading from the glass melting furnace. Channel 2 ends in a tray having side slopes 3 and sock 4, and the flow of liquid glass, usually soda-lime glass, is controlled by the adjustment flap 5. The tray with its sock 5 extends beyond the end wall of the 6 bath with a bottom 7, the outlet end wall 8 and the side walls 9. The bath contains molten metal 10, usually liquid tin or alloy 10, and liquid glass flows as shown at 11 through the nose of the tray 4 onto the surface of the molten metal 10 at the inlet end wall of the bath, where that and supported about 1000 ° C by the heaters 12, which are mounted on top of the tub 13 defining a cavity 14 above the surface of the molten bath 20'metalla. The upper part of the bath has an inlet end wall 15, which goes down and its lower end is located near the surface of the molten metal 10 at the 25 inlet end of the bath, providing a small gap 16 in height.
    The upper part of the bath structure also has a downwardly extending end part 17 at the outlet end. Between the lower surface of the end part of the upper part of the bath 13 and the upper surface of the end part 8 of the outlet end of the lower part of the bath, a gap 18 is formed for the glass tape to exit. Outside the gap 18, driven pulling rollers 19 are installed, the upper surface of which is located slightly higher than the upper surface of the end part 8 of the lower part of the bath. In the cavity 14 above the surface of the molten metal with a glass ribbon moving along it contains a protective atmosphere, consisting, for example, of 95% nitrogen and 57 hydrogen, which is supplied through pipelines 20 passing downward through the upper part 13 of the bath from the common pressure chamber 21. The protective atmosphere passes. dates through the inlet gap 16 to fill the cavity in which the tray is placed 50 . The temperature gradient along the length of the bath is maintained within. from about 1000 ° C. at the inlet end of the bath to a temperature of 570. 650 ° C. at the outlet end of the bath, where 55 glass tape exits the bath. At this low temperature, the glass has sufficient hardness so as not to experience any damage when it comes in contact with the pulling rollers 19, but at the same time it can be lifted from the surface of the molten metal.
    During the operation of the device, a silane-containing gas is supplied to the glass ribbon surface, consisting of silane in an amount of 0.1 to 20 vol.%, Hydrogen in an amount of 10 vol.% And an inert gas, usually nitrogen, in an amount of 70 to 99.9 vol. X, At a temperature ranging from 570 to 670 ° C, the silane in the gas mixture is easily decomposed by pyrolysis when it comes in contact with a hot glass surface, leaving silicon (Si) on the surface of the glass ribbon. Preferably, monosilane is used as the silane.
    The gas distributor 22 (FIG. 1) is presented in more detail in FIG. 2-3. The gas distributor contains a hollow conduit 23 of rectangular cross section, which is welded to the upper surface of the channel portion 24, which is U-shaped and serves as a channel for a cooling fluid, usually water. From each side wall of the channel along its length inwardly extend horizontally located pallets 25, between the inner ends of which an elongated slot or holes 26 are formed. On the horizontally arranged parts 25 there is another channel 27 of a U-shape that covers the slot 26. The lower edges of the channel 27 welded to the parts 25. Channel 27 serves to supply cover gas. Between the channels 27 and 24, another U-shaped channel 28 is formed, which serves for the flow of cooling water. The gas distributor, in addition, contains an oblong chamber 29 open on the front side, which, with its open side, is adjacent to the upper surface 30 of the moving glass strip and communicates along its entire length with the gas supply channel 27. The chamber open on the front side has a horizontally arranged tile 31 made of pressed heat-insulating fibrous material, the inner edges of these tiles forming an elongated slot or hole 32, which is in line with the slot 26 in the lower part of the gas supply channel. At the ends of the chamber 29, carbon walls 33 are installed, and each side wall of the chamber 29 5 is formed by two carbon tiles 34, which are connected to each other by a centrally located hinge, which is fixed to the side wall of the channel 24.
    A gas distributor is installed between the oblong slots 26 and 32 and includes base plates 35 supporting a centrally located layered corrugated plate 15 to 36 made of corrugated metal sheets. Base plates 35 are screw-fastened to horizontal pallets 25. A centrally located corrugated plate
    36 (FIG. 3) consists of a series of corrugated metal strips which are arranged so as to form cells between them, i.e. in the position out of alignment of the corrugations, as a result of which channels 37 of a small cross section are created compared to the cross section of the gas supply channel 27 so that when the gas containing silane is supplied under pressure to the channel 27 through gas pipelines, the pressure drop along the gas supply channel is small in compared with the differential pressure in the channels 37, and the corrugated plate 36 works effectively, which ensures the flow of cold silane-containing gas into the chamber 29 at constant pressure and temperature along the entire length of the specified chamber. However, it is desirable 40 that the chamber 29 is heated by radiating heat from the upper surface 30 of the glass tape, which extends below the open side of the camera, the gas distributor being installed so that the lower edge of the camera is located near the upper surface of the glass tape, which should be applied silicon coating (Fig.Z).
    The presence of heat-insulating tiles provides a condition under which the gas supply channel 27 and the corrugated plate 36 are maintained at a temperature below 400 ° C so that the silane does not decompose prematurely 55 and silicon does not deposit on the inner surface of the gas supply channel or on the corrugated plate. The carbon walls of the chamber 29 are maintained mainly at ambient temperature, as a result of which the cavity inside the chamber forms a heating zone into which the gas containing silane enters mainly at a constant temperature and pressure over the entire surface of the glass. Cooling water is supplied to one end of the gas distributor located outside the bath. The water supply pipe communicates with a channel 28, through which water flows to the other end of the distributor and then through an opening (not shown) to the upper part of the channel 24 of the U-shaped cross-section and the lower part of the pipeline 23 adjacent to it.
    The cooling water supplied in this way cools the parts 23, 24 and 27, which ensures the rigidity of the gas distributor, and the flow of gas containing silane through the channel 27 is maintained at a temperature approximately equal to the temperature of the cooling water, i.e. 40-50¾.
    The chamber 29 is located in the lower part of the gas distributor, in its central part, and in length corresponds to the widest glass ribbon to be coated as it moves along the bath. The elongated slot 26 therefore lies only in the central part of the gas supply channel 27 and in the direction of both ends of this channel, i.e. outside the chamber 29, the gas supply channel 27 and the cooling water supply channel 24 have a continuous base formed by one plate which is welded to the side walls of the channel 24.
    In FIG. 4 and 5 show two design options for the chamber, where the side walls 38 are made of carbon, have a significant thickness and are screwed to the base plates 35. In addition, intermediate heat-insulating tiles 31 are used. The walls 38 are shaped to calculate the desired cavity shape in the chamber, which has a narrow slot 32 in the upper part and a wide open side in the lower part. The inner surface of the side walls may be rounded.
    Smoother gas expansion and a different nature of the gas flow are created using a different configuration of the inner surfaces of the walls 38, where these surfaces are
    904513 8 are flat and inclined (Fig. 5).
    Another embodiment of the gas distributor is shown in FIG. 6, where 5 the chamber 29 open from the lower side is made to provide a laminar flow of the working gas parallel to the surface 30 of the glass tape.
    The gas distributor includes a U-shaped chamber 10 with side walls 39 and 40 and top 41. The chamber cavity is divided into two parts using a vertically arranged partition 42. Horizontal pallets 15 of pallet 43 and 44 extend inward from wall 39 and partition 42 in the lower part of the latter and an elongated slot forms between the inner ends of the horizontal parts
    2 ° or hole 45. The second U-shaped chamber is located symmetrically on top of the hole 45. Two U-shaped chambers, together with horizontal parts 43 and 25 44, form a U-shaped channel 46 for supplying cooling fluid. The rectangular channel 47 of the return flow of the cooling fluid is determined by the side wall 40, the top 41, the partition 42 and the horizontal tray 48. The inner surface of the U-shaped chamber 49 together with the horizontal parts 43 and 44 35 defines the gas pipeline 50. The gas distributor 51, represented by a corrugated plate 36, installed between the base plates 35, is screwed to the horizontal parts 43 and 40 44 so that the corrugated plate is aligned with the slot or 'hole 45. Shaped bogs 52-55 of carbon define the channel 55 of the 11-shaped cross section, the open side of which lies at the 45 _ _ cross of the upper surface 30 of the glass tape on which the coating is applied. Block 52 of carbon consists of an upper 56 and a lower 57 parts, between which is a layer 58 of fibrous insulation material. The carbon block 53 also consists of upper and lower parts, between which a layer of fibrous insulation material 55 is located . During operation of the device, the insulating layers control the degree of heat transfer between the cooled gas supply channel and channel 55.
    allowing heating of the shaped walls defining said chamber.
    The front sides of the carbon blocks 52-55, which define the walls of the U-shaped channel 55, are smooth and shaped in order to avoid turbulence in the flow and to ensure the laminar flow of gas along the surface 30 of the glass tape. The auxiliary carbon blocks 59 and 60 are fixed to the rear shaped side of the carbon block 55, respectively, at the upper and lower ends of the latter and serve to increase the ability to control the gas flow. The lower auxiliary unit is located horizontally near the gas surface and restricts the gas flow into the gap between the lower surface of the block 55 and the surface of the glass sheet.
    Example 1 relates to the deposition of a silicon coating on the upper surface of a glass tape obtained on the surface of a molten metal, before leaving the tape from the installation for the manufacture of such a glass tape. Example 2 relates to the deposition of a silicon coating on a strip of laminated sheet glass as it passes through a glass kiln.
    In the examples shown, the optical properties of the resulting glass are given. The thickness of the coating layer is determined by a known method for measuring optical thickness. The degree of transmittance of white light is determined using for this purpose, as a light source, the lighting means C in accordance with the provisions of the International Commission on Lighting.
    Example 1. The proposed device is used, and the protective atmosphere consists of 94 vol.% Nitrogen and 6 vol.% Hydrogen and is maintained in the cavity of the upper part of the bath over the molten metal, over which the glass tape moves. The glass tape is fed at a speed of 295 m / h, followed by passing through the glass annealing furnace. The gas distributor is installed near the outlet end of the bath, where the surface temperature of the glass is about 610 ° C, and the lower edge of the chamber 29 has -. as close as possible to the upper surface 30 of the glass tape, but without contact with the latter. A silane-containing gas consisting of
    3.9 vol.% Monosilane (Sill ^) ^ 93.0 vol.% Nitrogen and 2.2 vol.% Hydrogen, at a rate of 90 l / min per meter of distributor length. The feed rate is controlled until a substantially uniform silicon coating is obtained on the glass surface at the outlet end of the glass annealing furnace. The plates cut off from a ribbon of silicon-coated glass 5 are brown in transmitted light and silver in reflected light. The thickness, refractive index, optical properties of the coated glass were sle2 blowing 0: wavelength of maximum reflection (λ ™ αχ) 5340 A, a refractive index of 3.73 ', the optical thickness of 1234 A thickness 355 of white light transmittance of 23%, a direct 25 solar heat transmission 34%; total heat transmission 40%; reflection of solar radiation 48%.
    Example 2. The process is repeated as in example I using 30 for this purpose a modified version of the device (FIG. 6) when feeding silane-containing gas through the open side of the chamber parallel to the glass surface under conditions of a substantially laminar gas flow. The total gas flow rate is set based on ensuring uniform coating of the glass, and the concentration of ha force in the gas varies to change the coating thickness in order to obtain a given layer thickness. The coating conditions are as follows: the composition of the protective atmosphere is 90 vol.% Nitrogen, and 10 vol.% Hydrogen; the speed of the glass ribbon in the annealing furnace stack 45 la - 365 m / h; glass temperature 620 ° C ', the flow rate of the gas mixture is 50.0 l / min / m length of the distributor; · the composition of the gas mixture: | 5 vol.% Monosilane- (SiH ^) and 95 vol.% 50 nitrogen ', II - 10 vol.% Monosilane and 90 vol.% Nitrogen ”, lit - 7 vol.% Monosilane (S1H4), 3 vol.% Hydrogen and vol.% nitrogen.
    The thickness, refractive index and optical properties of the glass according to example 2 are presented in the table.
    H 904513 , 2
    -ηPhysical indicators -----Make upI gas mixtureg PT The wavelength of maximum reflection SD-minds) "A 4800 7100 0000 Refractive index 3.45 4.00 3.80 ABOUTOptical Thickness, A 1,190 1780 1,500 0Thickness, A 348 444 395 White light transmission,% 25 21 18
    Direct solar transmission
    heat% 37 24 28 Total heat transmission%  43 31 34 Reflection of solar radiation,% 43 54 52
    Glass color in conductive light
    Brown
    Green
    Brown
    Glass color in reflected light
    Silver
    Gold
    Silver
    Coated sheet glass can serve either as the inner or outer window glass of a double glazed product. In a multilayer glazed product containing three or more window panes, coated glass can be used as an intermediate window pane or as an internal window pane.
    In some cases where high-strength glass is required, it is desirable to make the glass more durable by conventional thermal improvement. Such a thermal improvement was carried out with respect to the silicon-coated glass according to the invention, with no significant deterioration of said coating. In addition, the glass provided with such a coating may be laminated.
    Silicon-coated glass has a pleasant appearance and can be used where special properties are not required with regard to controlling exposure to solar radiation, for example, with internal glazing or as a decorative and sometimes building material for furniture. For example, silicon-coated glass can be used to cover a table.
    In addition, silicon-coated glass can be used as a mirror by creating a dark back side to prevent light from passing through the glass. Such silicon coated mirrors are obtained by applying black paint either on top of the silicon coating or on the back of the glass. When applying a silicon coating as an integral part of the gas containing silane, you can use other silanes, for example, disilane or dichlorosilane (SiHgCLg).
    The method according to the invention is used for coating flat glass, the coating thickness being in the range of 200 to 1,000 A or more. Preferably, the coating thickness is in the range of 250 to 600 K.
    Thinner coatings within the specified limits are silver in reflected light and brown in transmitted light. As the thickness of the coating layer increases, its color gradually changes, for example, with a coating thickness of about 400 X, the glass appears yellow-silver in reflected light and brown in transmitted light.
    权利要求:
    Claims (2)
    [1]
    3  1SDIA of the method, which includes a support, a gas supply line for feeding the coating material, located across the glass ribbon, and an open chamber, the gas pipeline is equipped with a water jacket and is connected to the open chamber with a gas flow distributor.  In this device, the gas flow distributor is expediently made in the form of a series of vertical channels, heat-insulating plates are installed between the gas pipeline and the chamber, and the chamber is formed with shaped walls. The proposed method can be used for coating silicon and a mixture of silicon with other materials.  The preferred surface temperature of the glass for coating is 600-670 ° C.  The silane contained in the coating mixture is preheated before coating to a temperature of 400 ° C at which it is not. there is a significant decomposition of silane.  The thickness of the applied coating can be from 250 to 600 A, the refractive index of the coating is 3.0-4.0.  FIG.  1 shows an apparatus for making sheet glass on a molten metal surface. C.  showing the design of the molten metal bath and the gas distributor, which is installed across the movement of the sheet glass near the exit end of the device, section vertically, FIG.  2 - gas distributor, permitted in FIG. 3 - part of the gas distributor enlarged view; in fig.  4 - the same side walls are shaped and, in such a way, that they form a ears, a cavity dug in the direction of the open side of the chamber; in fig.  5 the same, the side walls forming the open side of the chamber have a different shape,} ha of FIG.  6 - the same, the camera has an open side; in fig.  7 An embodiment of a gas distributor for coating a glass in an annealing furnace for glass, a cross section.  Molten glass is fed in the usual way along channel 2 leading from a glass melting furnace.  Channel 2 terminates in a tray that plays out the side slopes 3 and the toe 4, with 4 than the flow of liquid glass, usually soda-lime glass, controlled by means of an adjusting flap 5.  . The tray with its toe extends beyond the end wall 6 of the bath, having a bottom 7, an outlet end wall 8 and side walls 9.  The bath contains molten - 1st metal 10, usually liquid tin or alloy, the liquid stream flows as indicated by the position 11, through the toe 4 of the tray to the surface of the molten metal 10 at the inlet end wall of the bath where the temperature is maintained at about 1000 C using heaters 12, which are mounted on the upper part 13 of the bath, defining the cavity 14 of the bath above the surface of the molten metal.  The upper part of the bath has an inlet end wall 15 which goes down and is located at its lower end near the surface of the molten metal 10 at the inlet end of the bath, providing a small gap 16 in height.  The upper part of the bath structure, in addition, has a downward end 17 at the outlet end.  A gap 18 is formed between the lower surface of the end portion of the upper part of the bath 13 and the upper surface of the end portion 8 of the outlet end of the lower part of the bath.  Outside the gap 8, driven pulling rollers 19 are installed, the upper surface of which is located slightly higher than the upper surface of the end part 8 in the lower part of the bath. In the cavity 14 above the surface of the molten metal with a glass ribbon moving along it there is a protective atmosphere, for example, 95 % nitrogen and 5% hydrogen, which is fed through pipelines 20 downwardly through the upper part 13 of the bath from the common pressure chamber 21.  The protective atmosphere of the passageway through the inlet gap 16 to fill the cavity in which the tray is placed, the temperature gradient along the length of the bath is kept within. from about 000 ° C at the end of the bath to a temperature of 570 ° C at the outlet end of the bath where the ribbon of glass comes out of.  In this low temperature disease, the glass has sufficient hardness not to suffer any damage when it comes in contact with pulling rollers 19, while at the same time allowing it to rise from the surface of the molten metal.  During operation of the device, a gas containing silane consisting of silane in an amount of from 0.1 to 20 vol. % hydrogen in quantity from 10 vol. % and inert gas, usually nitrogen, in an amount of from 70 to 99.9 vol. %  At temperatures ranging from 570 to 670 C, the silane in the gas mixture easily decomposes by pyrolysis when it comes into contact with the hot surface of the glass, leaving silicon (Si) on the surface of the glass ribbon.  Preferably, monosilane (51Nl) is used as the silane.  Gas distributor 22 (FIG. 1) is presented in more detail in FIG.  2-3.  The gas distributor contains a hollow pipe 23 of a rectangular section, which is welded to the upper surface of the portion 24 of the channel, which has a P-shaped shape and serves as a channel for a cooling fluid, usually water.  From each side wall of the channel along its entire length, horizontally arranged pallets 25 move inwards, between the inner ends of which an elongated slot or holes 26 are formed.  On the parts located horizontally, 25 is installed another channel 27 of the U-shaped form, which coats the slot 26.  The lower edges of channel 27 are welded to parts 25.  Channel 27 serves to provide cover gas.  Between channels 27 and 24, another U-shaped channel 28 is formed, which is a channel for cooling Bopfj.  The gas distributor, in addition, contains an elongated open from the front side chamber 29 which, with its open side, lies adjacent the upper surface 30 of the moving glass ribbon and communicates along its entire length with the gas supply channel 27.  The front side of the chamber is w-1ete horizontally located tile 31 of extruded heat insulating fibrous material, the inner edges of these tiles forming an elongated slot or hole 32, which is located in line 36 With a slot 26 in the lower part of the gas supply channel.  Walls of carbon 33 are installed at the ends of chamber 29, and each side wall of chamber 29 is formed by two carbon tiles 34, which are interconnected by means of a centrally located joint that is fixed to the side wall of channel 24, the gas distributor is installed between elongated slots 26 and 32 and includes base plates 35, bearing the centrally located laminated corrugated plate 36, made of corrugated metal sheets.  The base plates 35 are fastened with screws to the horizontal pallets 25, the centrally located corrugated plate 36 Gfig. H) consists of a series of corrugated metal strips, which are arranged so as to form between them the cells, t. e.  in a position out of coincidence the corrugation, as a result of which channels 37 of a small cross section are created compared to the cross section of the gas supply channel 27 so that when the silane-containing gas is supplied under pressure into the channel 27 through gas pipelines, the pressure differential along the gas creep channel is small in comparison with the pressure drop in the channels 37, and the corrugated plate 36 works efficiently, which ensures that Cold silane-containing gas enters the chamber 29 at constant pressure and temperature along the entire length of the said chamber.  It is desirable, however, that chamber 29 be heated by radiating heat from the upper surface 30 of a glass ribbon that extends below the open side of the chamber, and the gas distributor is installed so that the lower edge of the chamber is located near the upper surface of the glass ribbon to which should be applied: o silicon coating (FIG. H).  .  The presence of heat insulating tiles 31 ensures that the gas supply channel 27 and the corrugated plate 36 are maintained at a temperature below 400 ° C so that the silane does not decompose prematurely and silicon does not precipitate on the inner surface of the gas supply channel or on the corrugated plate.  The carbon wall 1 of the chamber 29 is maintained s / mainly at ambient temperature, 13 resulting in a cavity inside the chamber forming a heating zone into which the containing force enters the gas mainly at constant temperature and pressure over the entire surface of the glass.  The cooling water is supplied to one end of the gas distributor located outside the bath.  The water-conduit tube communicates with a channel 28 through which water flows to the other end of the distributor and then through an opening (not shown) to the upper part of the channel 24 of the U-shaped cross section and the lower part of the pipeline 23 adjacent to it.  Served in this way, cooling water oh. parts 23, 24 and 27 fall, which provides rigidity to the gas distributor, and the flow of silane-containing gas through channel 27 is maintained at a temperature approximately equal to the temperature of the cooling water, t. e.  40-50 0.  Chamber 29 is located in the lower part of the gas distributor, in its central part, and in length corresponds to the widest glass strip to be covered as it progresses along the bath.  The longitudinal slot 26 therefore runs only in the central part of the gas supply channel 27 and in the direction of the wallpaper of the ends of this channel, t. e.  outside the chamber 29, the gas supply channel 27 and the cooling water supply channel 24 have a continuous base formed by one plate, which is welded to the side walls of the channel 24.  FIG.  4 and 5 two chamber designs are shown, where the side plates 38 are made of carbon, are of considerable thickness and are screwed to the base plates 35.  In addition, intermediate telesolation tiles 31 are used.  The walls 38 are shaped to provide the desired shape of the cavity in the chamber, which has a narrow slot 32 in the upper part and a wide open side in the lower part.  The inner surface of the side walls may be rounded.  A smoother expansion of the gas and a different character of the gas flow are created using a different configuration of the internal surfaces of the walls 38, where these surfaces are flat and sloping (Fig. five).  Another design of the gas distributor is shown in FIG.  6, where the chamber 29 is open from the bottom side to be provided to provide a laminar flow of working gas parallel to the surface 30 of the glass ribbon.  The gas distributor includes an L-shaped section chamber with side walls 39 and 40 and a top 41.  The cavity of the chamber is divided into two parts with the help of a vertically located partition 42.  The horizontal pallets 43 and 44 move inward from the walls 39 and the partition 42 in the lower part of the latter, and an elongated slot or hole 45 is formed between the inner ends of the horizontal parts.  The second chamber of the U-shaped section is located symmetrically over the opening 45.  The two chambers of a U-shaped cross section, together with the horizontal parts 43 and 44, form a channel of the U-shaped cross section 46 for supplying a cooling fluid.  A rectangular section channel 47 of the reverse flow of the cooling fluid is determined by the side wall 40, top 41, partition 42 and horizontal pan 48.  The inner surface of the U-shaped chamber 49, together with the horizontal parts 43 and 44, defines the gas pipeline 50.  The gas distributor 51, represented by a corrugated plate 36, mounted between the support plates 35, is screwed to the horizontal parts 43 and 44 so that the corrugated plate is aligned in line with the recess OR hole 45.  Shaped 52-55 of carbon define a channel 55 of an i-shaped section, the open side of which lies across the upper surface 30 of a ribbon of glass to be coated.  The carbon block 52 consists of the upper 56 and lower 57 parts, between which there is a layer 58 of fibrous insulating material. The shaped block 53 of carbon also consists of the upper and lower parts, between which there is a layer of fibrous insulating material.  During operation of the device, the heat insulating layers control the degree of heat transfer between the cooled gas supply channel and the channel 55.  9 allows the heating of the shaped walls defining the specified chamber.  The front sides of the carbon blocks 52-55, which define the walls of the U-shaped channel 55, are smooth and shaped to avoid flow turbulence and to ensure laminar gas flow over the glass ribbon surface 30. The auxiliary carbon blocks 59 and 60 are fixed to the rear section of the carbon block 55, respectively, at the upper and lower ends of the latter, and serves to increase the ability to control the flow of gas. The lower auxiliary unit is located horizontally near the gas surface and limits Flowing gas into the gap between the bottom surface of the block 55 and the surface of the glass sheet. Example 1 relates to the deposition of a silicon coating on the top surface of a ribbon of glass produced on the surface of the molten glass. metal, before the tape leaves the installation for making such a glass tape.  Example 2 relates to the deposition of a silicon coating on a strip of rolled sheet glass as it passes through a glass burning furnace.  In the examples shown, the optical properties of the resulting steel are shown.  The thicknesses of the coating layer are determined by a known method for measuring the optical thickness.  The degree of transmission of white light is determined with the use of lighting means C for this purpose as the light source according to the provisions of the International Commission on Illumination.  Example I.  Use the proposed device, and the protective atmosphere consists of 9A vol. % nitrogen and 6 vol. % of hydrogen and is maintained in the cavity of the upper part of the bath on top of the molten metal, on top of which the ribbon of glass moves.  The glass ribbon is fed at a speed of 295 m / h, followed by passing through a glass annealing furnace.  The gas distributor is installed near the outlet end of the bath where the glass surface temperature is approximately, the lower edge of the chamber 29 is located as close as possible to the upper 310 surface 30 of the glass ribbon, but without contact with the latter. A silane gas consisting of 3.9 about % monosilane (Sill) 93.0 vol.% nitrogen and 2.2 vol. % hydrogen, at a rate of 90 l / min per meter of distributor length.  The feed rate is adjusted until a substantially uniform silicon coating is obtained on the surface of the glass at the exit end of the glass annealing furnace.  The plates, cut from a ribbon of glass coated with cream, are brown in the light of passing light and silver in light of the light.  The thickness, refractive index, optical properties of the provided glass coating were as follows: the maximum reflection wavelength (XyTiOtx) was 5340 L, the refractive index was 3.73; optical crowd 1234 A, thickness 355 A; white light transmission 23%, direct heat transmission of solar heat 34%, total heat transmission of 40%, reflection of solar radiation 48%.  Example 2  The process is repeated in Example I using a modified version of the device for this purpose (FIG. 6) when feeding gas containing silane through the open side of the chamber parallel to the glass surface under conditions of essentially laminar gas flow.  The total gas flow rate is set at the rate of providing uniform glass coating, and the concentration of force in the gas is varied to change the thickness of the coating in order to obtain a predetermined layer thickness.  Coating conditions are as follows: protective atmosphere composition - 90 vol. % nitrogen, and 10 vol. % hydrogen; the speed of the glass ribbon in the furnace for glass annealing is 365 m / h; glass temperature 620 ° C; feed rate of the gas mixture - 50.0 l / min / m of the distributor length; The composition of the gas mixture:) 5 vol. % monosilane- (511-14) and 95 vol. % nitrogen; II 10 about. % monosilane (Sill) and 90 vol. % of nitrogen: 1 (1 - 7 vol. % monosilane (51114), 3 vol. % hydrogen and 90 vol. % of nitrogen.  The thickness, the refractive index, and the optical properties of the glass in Example 2 are presented in the table.  Maximum reflection wavelength (Humoh) Break index of 3.45 o Optical thickness, A1190 o Thickness, L348 Transmission of white light,% 25 Direct transmission of solar heat,% Full transmission of heat,% Reflection of solar radiation,% Color of glass in transmitted light The color of the glass in reflected light. The coated sheet glass can serve as either an inner or outer window glass of a double glazed product. In a multi-layer glazed product containing three or more window glass glasses, provided with ytie glass can be used as an intermediate glass pane, or as vnutrenneg windowpane.  In cases where high strength glass is required, it is desirable to make the glass more durable by the usual thermal improvement.  This thermal improvement was carried out with respect to the silicon coated glass according to the invention, and no significant deterioration of said coating was noted.  In addition, the coated glass may be laminated.  Silicon-coated glass has a pleasing appearance and can be used where special properties are not required with respect to controlling exposure to solar radiation, for example, with internal glazing 00 b O4, 00 3.80 1/80 1500 444 395 Brown Green g Brown Silver Gold Silver or as a decorative and sometimes building material for furniture.  For example, silicon-coated glass can be used to cover a table.  In addition, silicon-coated glass can be used as a mirror by creating a dark back side to prevent light from passing through the glass.  Such silicon coated mirrors are obtained by applying a black ink either on top of the silicon coating or on the reverse side of the glass.  When applying a silicon coating, other silanes, such as disilane () or dia orsilane (SiHgCl. g)  The method according to the invention is used for coating flat glass, the coating thickness being in the range from 200 to 1000 A or more.  Preferably, the coating thickness is B ranging from 250 to 600 i.  The thinner coatings in the indicated limits have a silver color in the reflected light, and a brown color in the transmitted light 13.  As the thickness of the coating layer increases, a gradual change in its color takes place, for example, when the coating thickness is about 400 X, the glass looks yellow-silver in reflected light and brown in transmitted light.  Claim 1. The method of obtaining silicon coating on the surface of glass with a temperature of 400-700 ° C by pyrolysis of a mixture comprising silane and an inert gas, which, in order to obtain a uniform coating, is applied to the continuously moving one. glass ribbon across the entire width of cm b of the following composition, vol. %: 0.1-20 Silane Else Inert gas 2.  The method according to P. 1, that is, with the fact that the coating is nano, from a mixture containing an additional hydrogen - 2-10 vol. %   3 A device for the implementation of the manual on PP.  1, 2, including an opus, a gas pipeline for feeding the material of the opening, located across the glass and an open chamber, which is equipped with a water jacket and is connected to the open chamber by a gas distributor.  4 Device in PP.  1 to 3, in which the gas distributor is designed as a series of vertical channels, 5. Device on PP.  1-4, that is, insulating plates are installed between the gas pipeline and the chamber.  6, the Device in PP.  1-5, that is, so that the chamber is made with shaped walls.  Sources of information taken into account in the examination 1. U.S. Patent No. 3,821,020, cl.  117-106, published.  1974.  
    [2]
    2. The patent of France No. 2046320, cl. From 03 to 17/00, published 1971.
    904513
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    同族专利:
    公开号 | 公开日
    NZ177812A|1978-06-20|
    RO75159A|1981-03-30|
    NL7507071A|1975-12-16|
    IT1041380B|1980-01-10|
    GB1507465A|1978-04-12|
    LU72728A1|1975-10-08|
    CS209479B2|1981-12-31|
    DE2526209C3|1979-04-05|
    JPS5130219A|1976-03-15|
    DK267475A|1975-12-15|
    IN144078B|1978-03-18|
    FR2274572A1|1976-01-09|
    NO752111L|1975-12-16|
    IE41157L|1975-12-14|
    FR2274572B1|1982-01-29|
    ES438551A1|1977-02-01|
    DK154340C|1989-04-10|
    FI59238B|1981-03-31|
    NO140533C|1979-09-19|
    FI751752A|1975-12-15|
    DD120644A5|1976-06-20|
    SE7506768L|1975-12-15|
    DK154340B|1988-11-07|
    AR205204A1|1976-04-12|
    NO140533B|1979-06-11|
    FI59238C|1981-07-10|
    ATA455675A|1978-05-15|
    SE410591B|1979-10-22|
    TR18884A|1977-10-21|
    CH614916A5|1979-12-28|
    BE830179A|1975-12-12|
    AT347617B|1979-01-10|
    IE41157B1|1979-10-24|
    CA1048870A|1979-02-20|
    BR7503721A|1976-07-06|
    ES438550A1|1977-05-16|
    US4019887A|1977-04-26|
    JPS5531099B2|1980-08-15|
    ZA753807B|1976-05-26|
    DE2526209B2|1978-08-10|
    DE2526209A1|1976-01-02|
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    法律状态:
    优先权:
    申请号 | 申请日 | 专利标题
    GB26522/74A|GB1507465A|1974-06-14|1974-06-14|Coating glass|
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